This volume provides an update on the chemistry of manganese, technetium and rhenium covered in Volume 4 of COMC. The literature surveyed is from 1982 to 1993. The explosive growth in organorhenium chemistry, the use of manganese hydrocarbon complexes in organic synthesis, and the development of the chemistry of high oxidation manganese and rhenium compounds are highlighted. The growth of organotechnetium chemistry which was virtually unknown at the time of COMC is covered in depth.
Manganese Group, 1st Edition
Manganese Carbonyls and Manganese Carbonyl Halides (P.M. Treichel). Manganese Alkyls and Hydrides (T. Flood). Manganese Complexes Containing Nonmetallic Elements (P.M. Treichel). Manganese Hydrocarbon Complexes Excluding Cyclopentadienyl (K. McDaniel). Cyclopentadienyl Manganese Complexes (P.M. Treichel). Manganese Nitrosyl and Isonitrile Complexes (T. Flood). High Valent Organomanganese Compounds (G.S. Girolami, R.J. Morris). Technetium (A.P. Sattelberger, J.C. Bryan). Rhenium (J.M. O'Connor). High Valent Organorhenium Compounds (D.M. Hoffman).