José A.  Olabe

José A.  Olabe

Name: José Antonio OLABE Position: Research staff of CONICET Laboratory or research group: Coordination Chemistry Tel: 5411 4576-3378/89 ext.115 Fax: 5411 4576-3341 E-mail: Born in 1941, San Sebastián, Spain Studies in Chemistry: Doctor in Chemistry (1968), University of La Plata Postdoc: Inorganic Chemistry (Prof. P.J.Aymonino), La Plata (1969-70) Teaching Positions: Emeritus Professor, Facultad de Cs. Exactas y Nat., UBA Position at CONICET: Class I Researcher Topic of interest: Coordination Chemistry - Activation of small molecules - Catalysis Awards and Recognitions: Konex Award in Inorganic Chemistry, 2003. President of the Argentine Phys.Chem.Research Society, 2003-2005. Vice-Dean: Facultad de Cs. Exactas y Nat., UBA, 1990-1998. Invited Lecturer in National and International Meetings and Symposia. Selected Recent Publications - “Three Redox States of Nitrosyl: NO+, NO• and NO-/HNO Interconvert Reversibly on the Same Pentacyanoferrate(II) Platform”, A.C.Montenegro, V.T.Amorebieta, L.D.Slep, D.F.Martín, F.Roncaroli, D.H.Murgida, S.E.Bari, J.A.Olabe, Angew. Chem. Int. Ed. 2009, 48/23, 4213-4216. -“Addition and Redox Reactivity of Hydrogen Sulfides (H2S/HS-) with Nitroprusside: New Chemistry of Nitrososulfide Ligands”, S.L.Quiroga, A.E.Almaraz, V.T.Amorebieta, L.L.Perissinotti, J.A.Olabe, Chem. Eur. J., 2011, 17, 4145-4156. -“Disproportionation of O-Methylhydroxylamine catalyzed by aquapentacyanoferrate(II)”, M.M.Gutiérrez, J.A.Olabe, V.T.Amorebieta, Inorg. Chem. 2011, 50, 8817-8825. -“Nucleophilic Addition Reactions of the Nitroprusside Ion - The Case of O-Methylhydroxylamine”, M.M.Gutiérrez, J.A.Olabe, V.T.Amorebieta, Eur.J.Inorg.Chem. 2012, 4433-4438. - “Nitrosyl-Centered Redox and Acid-Base Interconversions in [Ru(Me3[9]aneN3)(bpy)(NO)]3,2,1+. The pKa of HNO for its Nitroxyl Derivative in Aqueous Solution”, N. Osa Codesido, T. Weihermüller, J. A. Olabe, L. D. Slep, Inorg. Chem. 2014, 53, 981-997. Other important Publications - “Reactivity of Reduced Nitroprusside, [Fe(CN)5NO•]3-, toward Oxygen”, M.Videla, F.Roncaroli, L.D.Slep, J.A.Olabe, J. Am. Chem. Soc., 2007, 129, 278-279. - “Release of NO from Reduced Nitroprusside Ion. Iron-Dinitrosyl Formation and NO-Disproportionation Reactions”, F.Roncaroli, R.van Eldik, J.A.Olabe, Inorg. Chem. 2005, 44, 2781-2790. - “Metal Catalyzed Anaerobic Disproportionation of Hydroxylamine. Role of Diazene and Nitroxyl Intermediates in the Formation of N2, N2O, NO+ and NH3”, G.E.Alluisetti, A.E.Almaraz, V.T.Amorebieta, F.Doctorovich, J.A. Olabe, J. Am. Chem. Soc. 2004, 126, 13432-13442. Reviews and Book Chapters -“Chemistry of Bound Nitrogen Monoxide and Related Redox Reactions”, J. A. Olabe, en Physical Inorganic Chemistry: Reactions, Processes, and Applications, A. Bakac, Ed., Wiley, 2010, Cap. 7, (ISBN 0470224207). -“The coordination chemistry of nitrosyl in cyanoferrates. An exhibit of bioinorganic relevant reactions”,(Perspective Article), JA.Olabe, Dalton Transactions, 2008, 3633-3648. -“New Features on the Redox Coordination Chemistry of Metal Nitrosyls {(M-NO+; M-NO•; M-NO?/HNO)}”, F. Roncaroli, M. Videla, L.D. Slep, J.A. Olabe, Coord. Chem. Rev., 2007, 251, 1903-1930. -“Redox Reactivity of Coordinated Ligands in Pentacyano(L)Ferrate Complexes”, J.A. Olabe, Adv. Inorg. Chem. 2004, 55, 61-126. -“Reactivity and Structure of Complexes of Small Molecules: Nitric and Nitrous Oxide”, J.A. Olabe, L.D.Slep, in: Comprehensive Coordination Chemistry II, From Biology to Nanotechnology, J.A. Mc Cleverty y T.J. Meyer, Eds., Pergamon, Vol. 1, Section III, Cap. 1.31, 2003, 603-623.

Affiliations and Expertise

Universidad de Buenos Aires, Argentina


Editors: Rudi van Eldik & José  Olabe Release Date: 08 Jan 2015
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